1

安益谱7700气质联用仪

1

包括单毛细管柱进样口、质谱主机、机械泵

2

色谱柱DB-5MS 30m×0.25mm×0.25µm

1

或其他等效色谱柱

3

高纯氦气、减压阀

1

4

计算机

1

Win10双核4G以上内存64位系统

1

N-亚硝基二甲胺

62-75-9

4.036

1

42

74、43

2

2-氟酚（替代物）

367-12-4

5.635

1

112

64、92

3

苯酚-d₆（替代物）

13127-88-3

6.890

1

99

71

4

苯酚

108-95-2

6.905

1

94

66、40

5

双（2-氯乙基）醚

111-44-4

7.020

1

93

63、95

6

2-氯苯酚

95-57-8

7.074

1

128

93、63

7

1,3-二氯苯

541-73-1

7.272

1

146

111、75

8

1,4-二氯苯-D₄

（内标1）

3855-82-1

7.325

1

150

115

9

1,4-二氯苯

106-46-7

7.340

1

146

148、111

10

1,2-二氯苯

95-50-1

7.614

1

146

148、111

11

2-甲基苯酚

95-48-7

7.758

1

108

107、77

12

二(2-氯异丙基)醚

108-60-1

7.811

1

121

123、77、79

13

六氯乙烷

67-72-1

8.063

1

117

109、201

14

N-亚硝基二正丙胺

621-64-7

8.017

1

43

70、130

15

4-甲基苯酚

106-44-5

7.971

1

107

108、77

16

硝基苯-d₅（替代物）

4165-60-0

8.177

1

82

128、54

17

硝基苯

98-95-3

8.207

1

77

123、51

18

异佛尔酮

78-59-1

8.569

1

82

138、54

19

2-硝基苯酚

88-75-5

8.689

2

139

65、81

20

2 ,4-二甲基苯酚

105-67-9

8.771

2

107

122、77

21

二（2-氯乙氧基）甲烷

111-91-1

8.935

2

93

63、123

22

2 ,4-二氯苯酚

120-83-2

9.044

2

162

164、63

23

1,2,4-三氯苯

120-82-1

9.180

2

147

74、109

24

萘-d₈（内标2）

1146-65-2

9.241

2

136

108

25

萘

92-20-3

9.268

2

128

129

26

4-氯苯胺

106-47-8

9.398

2

127

129、65

27

六氯丁二烯

87-68-3

9.568

2

118

260、223

28

4-氯-3-甲基苯酚

59-50-7

10.206

2

107

142、144、77

29

2-甲基萘

91-57-6

10.418

2

142

141、115

30

六氯环戊二烯

77-47-4

10.895

3

130

239、235

31

2,4,6-三氯苯酚

88-06-2

11.076

3

196

198、200

32

2,4,5-三氯苯酚

95-95-4

11.149

3

196

198、200

33

2-氟联苯（替代物）

321-60-8

11.282

3

172

171、170

34

2-氯萘

91-58-7

11.475

3

162

127

35

2-硝基苯胺

88-74-4

11.875

3

138

65、92

36

苊烯

208-96-8

12.694

3

152

76

37

邻苯二甲酸二甲酯

131-11-3

12.636

3

163

77

38

2 ,6-二硝基甲苯

606-20-2

12.826

3

165

63、89

39

苊-d₁₀（内标3）

15067-26-2

13.275

3

164

162、160

40

3-硝基苯胺

99-09-2

13.269

3

65

92、138

41

2 ,4-二硝基苯酚

51-28-5

13.672

3

184

63、154

42

苊

83-32-9

13.390

3

153

76

43

二苯并呋喃

132-64-9

14.062

3

168

139

44

4-硝基苯酚

100-02-7

14.126

3

139

65、109

45

2 ,4-二硝基甲苯

121-14-2

14.418

3

165

89、63

46

芴

86-73-7

15.779

3

166

163、82

47

邻苯二甲酸二乙酯

84-66-2

16.015

3

149

177

48

4-氯苯基苯基醚

7005-72-3

16.022

3

204

141、77

49

4-硝基苯胺

100-01-6

16.292

3

65

138、108

50

4,6-二硝基-2-甲基苯酚

534-52-1

16.548

3

198

51、105

51

偶氮苯

103-33-3

16.879

3

77

182、51

52

2 ,4 ,6-三溴苯酚

（替代物）

118-79-6

17.250

3

332

62、143

53

4-溴二苯基醚

101-55-3

18.890

4

250

141、77

54

六氯苯

118-74-1

19.511

4

284

286、282

55

五氯苯酚

87-86-5

20.815

4

266

264

56

菲-d₁₀（内标4）

1517-22-2

21.409

4

188

80

57

菲

85-01-8

21.557

4

178

176、179

58

蒽

120-12-7

21.848

4

178

176、179

59

咔唑

86-74-8

23.285

4

167

166、139

60

邻苯二甲酸二正丁酯

84-74-2

27.434

4

149

150、76

61

荧蒽

206-44-0

30.050

4

202

200、203

62

芘

129-00-0

31.556

5

202

200、201

63

4,4’-三联苯-d₁₄

（替代物）

1718-51-0

33.813

5

244

245、243

64

邻苯二甲酸丁基苄基酯

85-68-7

38.649

5

149

91、206

65

苯并（a）蒽

56-55-3

40.871

5

228

226、229

66

䓛-d₁₂（内标5）

1719-03-5

41.016

5

240

236、241

67

䓛

218-01-9

41.185

5

228

226、229

68

邻苯二甲酸二（2-二乙基己基）酯

117-81-7

43.931

5

149

167、57

69

邻苯二甲酸二正辛酯

117-84-0

48.458

6

149

279

70

苯并（b）荧蒽

205-99-2

48.615

6

252

126、250

71

苯并（k）荧蒽

207-08-9

48.805

6

252

126、250

72

苯并（a）芘

50-32-8

50.595

6

252

250、253

73

苝- d₁₂（内标6）

1520-96-3

51.023

6

264

260、263

74

茚并（1,2,3-cd）芘

193-39-5

57.342

6

276

138、274

75

二苯并（ah）蒽

53-70-3

57.683

6

278

139、276

76

苯并（ghi）苝

191-24-2

58.656

6

276

138、274

1

4.058

0.10

1

177127.8

187170.2

5.40

4.058

2

178425.6

4.058

3

184488.1

4.058

4

183756.8

4.050

5

201066.5

4.050

6

198156.6

2

5.649

0.10

1

481615.8

478655.0

5.16

5.656

2

456851.4

5.655

3

494465.1

5.649

4

445802.6

5.647

5

479296.5

5.640

6

513898.4

3

6.905

0.02

1

661833.8

680346.9

7.89

6.904

2

715081.8

6.903

3

653631.8

6.905

4

764068.3

6.902

5

608619.4

6.904

6

678846.4

4

6.920

0.04

1

847481.7

882679.9

7.94

6.920

2

796684.6

6.926

3

853459.6

6.920

4

899218.3

6.917

5

895542.5

6.920

6

1003692.8

5

7.041

0.05

1

670501.2

753002.7

10.02

7.041

2

724710.0

7.039

3

874899.4

7.034

4

753044.4

7.038

5

801946.7

7.034

6

692914.3

6

7.087

0.04

1

701165.2

740108.2

3.53

7.087

2

722044.5

7.085

3

740441.6

7.087

4

751254.1

7.084

5

777287.0

7.080

6

748456.7

7

7.284

0.04

1

1096766.4

1122945.0

2.47

7.284

2

1101431.4

7.290

3

1104075.9

7.285

4

1168115.5

7.282

5

1139200.7

7.286

6

1128079.8

8

7.338

0.03

1

1418626.4

1425733.5

2.88

7.338

2

1351772.0

7.344

3

1443082.9

7.338

4

1429552.3

7.342

5

1475632.4

7.339

6

1435735.2

9

7.361

0.04

1

1288663.6

1348528.1

4.37

7.361

2

1283264.8

7.359

3

1381088.0

7.361

4

1336098.7

7.358

5

1363859.6

7.354

6

1438193.7

10

7.634

0.03

1

1010683.1

993373.5

2.88

7.634

2

983721.2

7.632

3

963517.1

7.628

4

968091.1

7.631

5

1039977.1

7.629

6

994251.6

11

7.771

0.03

1

568456.0

576298.1

11.57

7.770

2

551200.6

7.769

3

488277.9

7.773

4

567940.9

7.768

5

692673.0

7.773

6

589240.3

12

7.825

0.03

1

189295.6

198982.9

5.79

7.824

2

185018.8

7.822

3

205663.3

7.826

4

193352.6

7.821

5

205625.9

7.826

6

214941.2

13

8.076

0.02

1

299003.7

308529.3

3.72

8.074

2

295554.7

8.073

3

323742.9

8.076

4

305898.2

8.073

5

320990.4

8.077

6

305986.0

14

8.030

0.03

1

230466.3

237376.2

3.35

8.036

2

228257.7

8.036

3

236097.0

8.031

4

236228.5

8.034

5

249112.7

8.031

6

244094.9

15

7.992

0.03

1

907723.9

929367.7

2.53

7.991

2

904351.5

7.990

3

934561.5

7.985

4

918989.3

7.989

5

945693.9

7.986

6

964885.8

16

8.198

0.04

1

633899.5

682656.2

4.18

8.196

2

691752.7

8.196

3

686129.2

8.190

4

670674.3

8.195

5

694783.6

8.191

6

718697.6

17

8.221

0.02

1

817280.9

857034.9

3.57

8.219

2

828616.3

8.218

3

845836.4

8.220

4

877719.9

8.217

5

888190.8

8.222

6

884565.1

18

8.583

0.03

1

1541751.6

1472456.3

4.44

8.580

2

1406051.9

8.576

3

1470160.8

8.578

4

1443995.8

8.577

5

1560361.6

8.579

6

1412416.0

19

8.703

0.02

1

261990.8

254269.6

4.71

8.706

2

233403.7

8.701

3

262852.8

8.703

4

246287.2

8.701

5

262182.4

8.704

6

258900.7

20

8.785

0.02

1

467193.3

450834.3

7.20

8.782

2

447745.4

8.783

3

472746.2

8.785

4

390843.7

8.783

5

480667.9

8.786

6

445809.3

21

8.947

0.02

1

763683.6

814640.5

7.63

8.946

2

743565.6

8.946

3

785155.6

8.943

4

820152.7

8.947

5

895568.3

8.944

6

879717.0

22

9.056

0.02

1

782185.2

808492.5

3.67

9.060

2

791017.5

9.060

3

773177.2

9.058

4

828671.7

9.055

5

839354.3

9.058

6

836549.2

23

9.192

0.02

1

126706.0

135892.1

4.94

9.196

2

135526.9

9.197

3

132848.7

9.195

4

133201.8

9.197

5

145436.0

9.195

6

141633.0

24

9.252

0.02

1

1932429.3

1975405.9

3.21

9.251

2

1898306.1

9.251

3

1949486.1

9.255

4

1980262.5

9.251

5

2016748.7

9.250

6

2075202.5

25

9.279

0.02

1

1768163.3

1814043.2

5.64

9.278

2

1792114.4

9.278

3

1742879.3

9.282

4

1723874.2

9.278

5

2000183.3

9.277

6

1857044.6

26

9.410

0.01

1

630842.7

679463.2

5.68

9.408

2

647583.9

9.409

3

738671.1

9.408

4

674249.7

9.410

5

702411.5

9.408

6

683020.0

27

9.579

0.03

1

111723.6

121400.0

6.46

9.583

2

112155.3

9.578

3

122903.2

9.576

4

123451.2

9.578

5

130414.3

9.577

6

127752.1

28

10.221

0.02

1

477239.1

506198.3

4.56

10.218

2

489806.5

10.217

3

515888.5

10.216

4

492196.2

10.219

5

535152.6

10.217

6

526907.1

29

10.433

0.01

1

1415417.8

1439680.4

3.14

10.436

2

1372205.7

10.434

3

1457082.2

10.434

4

1430544.2

10.436

5

1505772.9

10.434

6

1457059.4

30

10.910

0.02

1

27821.8

27101.5

4.58

10.908

2

25807.8

10.911

3

26947.0

10.912

4

27019.2

10.910

5

29112.0

10.906

6

25901.2

31

11.098

0.02

1

666589.9

689428.9

3.62

11.095

2

657490.2

11.094

3

683918.0

11.093

4

695272.7

11.091

5

720216.8

11.093

6

713085.8

32

11.164

0.02

1

728214.4

742225.3

3.61

11.167

2

705163.5

11.166

3

737488.7

11.166

4

737045.4

11.164

5

780127.4

11.160

6

765312.2

33

11.298

0.01

1

1807975.9

1874026.2

4.31

11.301

2

1782107.4

11.299

3

1863842.2

11.299

4

1868627.1

11.297

5

2009138.1

11.299

6

1912466.4

34

11.498

0.02

1

1808741.9

1832532.5

2.36

11.494

2

1774926.7

11.492

3

1823752.8

11.492

4

1845935.8

11.497

5

1904267.3

11.492

6

1837570.2

35

11.896

0.02

1

395336.7

406209.9

2.97

11.893

2

391998.5

11.892

3

403171.0

11.892

4

407559.1

11.890

5

423951.9

11.892

6

415242.3

36

12.722

0.03

1

2230065.5

2304487.1

2.89

12.718

2

2242904.7

12.722

3

2298226.3

12.717

4

2296871.3

12.714

5

2407410.3

12.716

6

2351444.7

37

12.664

0.02

1

1804634.8

1861625.0

3.13

12.660

2

1786961.0

12.664

3

1869726.5

12.660

4

1875192.5

12.663

5

1946982.3

12.658

6

1886252.8

38

12.854

0.02

1

380759.1

393325.8

3.51

12.850

2

377110.6

12.854

3

391214.4

12.855

4

395888.4

12.852

5

415297.3

12.849

6

399684.8

39

13.303

0.02

1

1531443.1

1575709.4

3.06

13.298

2

1520638.7

13.302

3

1564696.4

13.298

4

1588707.1

13.295

5

1652764.0

13.298

6

1596006.9

40

13.297

0.02

1

298722.2

311359.8

3.59

13.298

2

301611.8

13.296

3

307737.8

13.292

4

311624.4

13.295

5

327774.3

13.292

6

320688.4

41

13.700

0.02

1

49665.4

50182.0

5.24

13.701

2

46533.9

13.704

3

49600.3

13.701

4

50442.9

13.704

5

54719.1

13.695

6

50130.3

42

13.418

0.02

1

1806261.4

1818152.6

3.55

13.419

2

1718939.5

13.423

3

1855701.2

13.419

4

1780274.3

13.416

5

1904045.9

13.418

6

1843693.4

43

14.097

0.02

1

2293615.4

2357560.8

2.88

14.092

2

2280775.6

14.095

3

2340346.9

14.091

4

2360765.1

14.095

5

2454882.1

14.091

6

2414979.8

44

14.091

0.02

1

661605.5

688193.0

2.69

14.092

2

673484.1

14.095

3

691092.6

14.091

4

699835.5

14.089

5

713569.7

14.085

6

689570.7

45

14.458

0.01

1

502066.6

517052.9

3.06

14.454

2

500975.5

14.457

3

511952.0

14.453

4

516683.0

14.456

5

541371.7

14.454

6

529268.5

46

15.818

0.03

1

1643859.5

1691451.3

4.02

15.815

2

1598620.1

15.817

3

1668706.0

15.811

4

1727269.8

15.809

5

1789464.9

15.809

6

1720787.6

47

16.055

0.02

1

1323108.3

1364410.9

4.27

16.052

2

1279622.1

16.053

3

1356682.9

16.048

4

1408387.6

16.052

5

1441437.4

16.044

6

1377227.3

48

16.061

0.03

1

912685.2

919928.5

3.00

16.065

2

884029.9

16.060

3

911603.4

16.055

4

910153.3

16.058

5

965365.4

16.051

6

935733.7

49

16.338

0.01

1

183770.2

193764.7

4.59

16.335

2

187333.4

16.336

3

191323.5

16.331

4

191012.4

16.335

5

202776.9

16.334

6

206371.8

50

16.588

0.02

1

70377.6

71404.9

4.76

16.592

2

67274.0

16.593

3

69524.4

16.588

4

71144.4

16.591

5

77234.7

16.585

6

72874.2

51

16.918

0.02

1

1538968.6

1585990.1

2.26

16.922

2

1547733.4

16.916

3

1590011.1

16.913

4

1599665.2

16.914

5

1630917.5

16.915

6

1608644.7

52

17.288

0.02

1

338610.9

348171.4

3.61

17.287

2

335414.8

17.288

3

342574.7

17.284

4

345391.6

17.284

5

366964.9

17.280

6

360071.7

53

18.934

0.02

1

489197.5

507617.0

3.03

18.925

2

492556.3

18.926

3

503971.7

18.929

4

510824.6

18.923

5

527390.8

18.925

6

521760.9

54

19.554

0.02

1

700265.2

733988.7

3.63

19.553

2

709372.8

19.546

3

733464.9

19.549

4

736649.6

19.544

5

751776.0

19.546

6

772403.5

55

20.863

0.02

1

355421.2

368794.7

3.62

20.856

2

361593.3

20.862

3

360712.4

20.859

4

364051.2

20.857

5

382680.0

20.853

6

388310.0

56

21.456

0.02

1

2437687.2

2491053.4

2.86

21.450

2

2416656.9

21.456

3

2452208.5

21.446

4

2482628.9

21.444

5

2572333.0

21.448

6

2584806.0

57

21.604

0.02

1

2460098.0

2521679.4

2.90

21.598

2

2454164.5

21.597

3

2511185.8

21.594

4

2494720.3

21.599

5

2647542.9

21.596

6

2562364.6

58

21.893

0.01

1

2388335.7

2458574.1

3.10

21.894

2

2392823.9

21.894

3

2404435.4

21.890

4

2468371.0

21.889

5

2565515.8

21.886

6

2531962.8

59

23.336

0.02

1

1201156.4

1274600.3

4.85

23.332

2

1243099.1

23.331

3

1253487.8

23.326

4

1255138.1

23.331

5

1321958.0

23.324

6

1372762.1

60

27.479

0.01

1

3072092.1

3189156.2

3.14

27.481

2

3127122.1

27.480

3

3140411.8

27.476

4

3175984.7

27.478

5

3289178.2

27.474

6

3330148.3

61

30.092

0.01

1

3161366.6

3282206.1

3.45

30.088

2

3232530.5

30.088

3

3244430.8

30.084

4

3208517.0

30.084

5

3405883.7

30.082

6

3440508.2

62

31.599

0.02

1

3293266.2

3437411.9

3.64

31.586

2

3383888.8

31.594

3

3394428.5

31.584

4

3372309.4

31.590

5

3560059.8

31.594

6

3620518.8

63

33.861

0.02

1

1850708.5

1934014.6

4.05

33.859

2

1901264.7

33.851

3

1904456.0

33.854

4

1892134.3

33.852

5

1993202.9

33.845

6

2062321.3

64

38.688

0.01

1

1395348.0

1458147.0

3.68

38.686

2

1447441.7

38.683

3

1440360.6

38.676

4

1431776.0

38.680

5

1482441.0

38.682

6

1551514.9

65

40.908

0.01

1

2482261.4

2844571.5

10.58

40.900

2

2529773.4

40.909

3

2853177.3

40.910

4

2860150.9

40.907

5

3105167.7

40.913

6

3236898.

66

41.053

0.02

1

2332757.9

2442142.4

4.12

41.051

2

2398753.1

41.036

3

2427807.4

41.031

4

2389298.9

41.046

5

2483051.5

41.046

6

2621185.6

67

41.228

0.01

1

2448426.3

2624061.8

5.18

41.227

2

2500586.6

41.224

3

2585553.0

41.218

4

2697987.4

41.227

5

2708724.2

41.228

6

2803093.2

68

43.961

0.01

1

2253748.1

2339405.8

3.85

43.965

2

2309832.4

43.957

3

2321758.9

43.955

4

2273709.0

43.955

5

2375721.2

43.957

6

2501665.4

69

48.494

0.01

1

4267157.5

4419700.4

3.61

48.493

2

4400445.0

48.488

3

4368245.3

48.481

4

4289424.1

48.484

5

4492674.5

48.485

6

4700256.2

70

48.645

0.01

1

2678524.4

2753042.8

5.02

48.644

2

2566420.1

48.644

3

2755527.6

48.632

4

2713024.7

48.635

5

2836138.5

48.647

6

2968621.6

71

48.840

0.00

1

2725374.8

2779368.0

6.06

48.844

2

2507718.4

48.839

3

2797939.0

48.838

4

2761580.9

48.840

5

2864856.7

48.842

6

3018737.9

72

50.630

0.02

1

2535995.6

2628463.3

3.74

50.634

2

2591571.4

50.613

3

2614408.1

50.632

4

2556991.8

50.625

5

2665356.7

50.633

6

2806456.2

73

51.057

0.01

1

2513370.3

2625724.8

4.14

51.061

2

2597675.7

51.062

3

2583694.4

51.048

4

2558940.8

51.063

5

2685124.9

51.065

6

2815542.6

74

57.388

0.01

1

2896353.2

2985528.9

3.43

57.379

2

2971958.6

57.370

3

2949897.5

57.375

4

2903439.0

57.380

5

3018240.2

57.387

6

3173284.8

75

57.718

0.01

1

2759966.9

2855799.9

3.43

57.719

2

2840900.4

57.711

3

2826670.2

57.705

4

2785772.5

57.709

5

2887244.6

57.712

6

3034244.5

76

58.686

0.01

1

2686306.2

2783595.0

3.34

58.686

2

2775288.3

58.679

3

2749104.7

58.672

4

2722124.1

58.673

5

2819989.2

58.685

6

2948757.6

1

N-亚硝基二甲胺

20

0.1500

0.077

2

2-氟酚（替代物）

809

0.0037

0.068

3

苯酚-d₆（替代物）

236

0.0127

0.061

4

苯酚

1441

0.0021

0.074

5

双（2-氯乙基）醚

995

0.0030

0.076

6

2-氯苯酚

1734

0.0017